The study aims to investigate how the mechanics of swelling of a polymer gel is affected by the presence of free-chains due to a partial cross-linking process. The analysis is focused on the equilibrium solution of the mechano-diffusion problem under different as-prepared states, corresponding to different polymer network fractions before diffusion starts. The limit situations of perfectly cross-linked polymer gel and solution of polymeric chains are recovered by the model.
Swelling-driven mechanics of partially cross-linked polymer gels: Steady state solutions / Nardinocchi, Paola; Ommi, Siddhartha H.; Sciarra, Giulio. - In: INTERNATIONAL JOURNAL OF ENGINEERING SCIENCE. - ISSN 0020-7225. - 202:(2024), p. 104101. [10.1016/j.ijengsci.2024.104101]
Swelling-driven mechanics of partially cross-linked polymer gels: Steady state solutions
Nardinocchi, Paola
;Ommi, Siddhartha H.;
2024
Abstract
The study aims to investigate how the mechanics of swelling of a polymer gel is affected by the presence of free-chains due to a partial cross-linking process. The analysis is focused on the equilibrium solution of the mechano-diffusion problem under different as-prepared states, corresponding to different polymer network fractions before diffusion starts. The limit situations of perfectly cross-linked polymer gel and solution of polymeric chains are recovered by the model.File | Dimensione | Formato | |
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