The oxidation of a series of aryl 1-methyl-1-phenylethyl sulfides with H2O2catalyzed by the two tetradentate nonheme-iron complexes [(PDP)FeII(SbF6)2] and [(BPMCN)FeII(OTf)2] occurs by an electron transfer-oxygen transfer (ET/OT) mechanism as supported by the observation of products deriving from fragmentation of the corresponding radical cations in association with S-oxidation products (sulfoxides). © 2017 Taylor & Francis Group, LLC.
Role of electron transfer processes in the oxidation of aryl sulfides catalyzed by nonheme iron complexes / Barbieri, Alessia; DI STEFANO, Stefano; Lanzalunga, Osvaldo; Lapi, Andrea; Mazzonna, Marco; Olivo, Giorgio. - In: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS. - ISSN 1042-6507. - STAMPA. - 192:2(2017), pp. 241-244. [10.1080/10426507.2016.1255623]
Role of electron transfer processes in the oxidation of aryl sulfides catalyzed by nonheme iron complexes
Barbieri, Alessia;Di Stefano, Stefano;Lanzalunga, Osvaldo
;Lapi, Andrea;Mazzonna, Marco;Olivo, Giorgio
2017
Abstract
The oxidation of a series of aryl 1-methyl-1-phenylethyl sulfides with H2O2catalyzed by the two tetradentate nonheme-iron complexes [(PDP)FeII(SbF6)2] and [(BPMCN)FeII(OTf)2] occurs by an electron transfer-oxygen transfer (ET/OT) mechanism as supported by the observation of products deriving from fragmentation of the corresponding radical cations in association with S-oxidation products (sulfoxides). © 2017 Taylor & Francis Group, LLC.| File | Dimensione | Formato | |
|---|---|---|---|
|
Barbieri_Role_2017.pdf
solo gestori archivio
Note: https://www.tandfonline.com/doi/full/10.1080/10426507.2016.1255623
Tipologia:
Versione editoriale (versione pubblicata con il layout dell'editore)
Licenza:
Tutti i diritti riservati (All rights reserved)
Dimensione
827.58 kB
Formato
Adobe PDF
|
827.58 kB | Adobe PDF | Contatta l'autore |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
