The behaviour of serine as a ligand towards cadmium(II) has been studied at 25°C in 3.00M NaCLO4 by measuring the electromotive force of galvanic cells containing cadmium amalgam and glass electrodes. The experimental data can be explained by assuming the existence of the following species: CdL−. CdHL2−. CdL2. CdH2L2− 2. CdL− 3, CdHL3 and CdH2L− 3. The stability constants have been determined. Good agreement between experimental and calculated values supports the validity of the model.
Serine as ligand: Complex formation with cadmium(II) / Bottari, Emilio Giovanni; Festa, Maria Rosa; Jasionowska, Renata. - In: JOURNAL OF COORDINATION CHEMISTRY. - ISSN 0095-8972. - STAMPA. - 17:(1988), pp. 245-253. [10.1080/00958978808070775]
Serine as ligand: Complex formation with cadmium(II).
BOTTARI, Emilio Giovanni;FESTA, Maria Rosa;JASIONOWSKA, Renata
1988
Abstract
The behaviour of serine as a ligand towards cadmium(II) has been studied at 25°C in 3.00M NaCLO4 by measuring the electromotive force of galvanic cells containing cadmium amalgam and glass electrodes. The experimental data can be explained by assuming the existence of the following species: CdL−. CdHL2−. CdL2. CdH2L2− 2. CdL− 3, CdHL3 and CdH2L− 3. The stability constants have been determined. Good agreement between experimental and calculated values supports the validity of the model.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
