The complexes formed between iron(II) and some aromatic anions (benzoate and 4-aminoderivate, salicylate and 4-aminoderivate, thiosalicylate) have been investigated in dimethylsulphoxide (DMSO). The complexation ratios and the stability constants of the species have been determined at 25 °C and compared, when possible, with the data obtained in ethanol. The results allow us to discuss the effect of the solvent properties and of the substituent position on the aromatic ring
Formation on iron(II) complexes with some aromatic anions in DMSO / Bucci, Remo; Carunchio, Vincenzo Tito; Girelli, Anna Maria. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 141:1(1988), pp. 99-102. [10.1016/S0020-1693(00)86382-3]
Formation on iron(II) complexes with some aromatic anions in DMSO
BUCCI, Remo;CARUNCHIO, Vincenzo Tito;GIRELLI, Anna Maria
1988
Abstract
The complexes formed between iron(II) and some aromatic anions (benzoate and 4-aminoderivate, salicylate and 4-aminoderivate, thiosalicylate) have been investigated in dimethylsulphoxide (DMSO). The complexation ratios and the stability constants of the species have been determined at 25 °C and compared, when possible, with the data obtained in ethanol. The results allow us to discuss the effect of the solvent properties and of the substituent position on the aromatic ringI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
