The gamma-butyrolactone formation by umpolung of alpha,beta-unsaturated aldehydes was catalyzed, in ionic liquids, by electrogenerated N-heterocyclic carbenes. The ionic liquids were used in the double role of pre-catalysts and solvents. (C) 2011 Elsevier B.V. All rights reserved.
Umpolung of alpha,beta-unsaturated aldehydes by electrogenerated NHCs in ionic liquids: Synthesis of gamma-butyrolactones / Monica, Orsini; Chiarotto, Isabella; Michelle M. M., Feeney; Feroci, Marta; Giovanni, Sotgiu; Inesi, Achille. - In: ELECTROCHEMISTRY COMMUNICATIONS. - ISSN 1388-2481. - STAMPA. - 13:7(2011), pp. 738-741. [10.1016/j.elecom.2011.04.025]
Umpolung of alpha,beta-unsaturated aldehydes by electrogenerated NHCs in ionic liquids: Synthesis of gamma-butyrolactones
CHIAROTTO, Isabella;FEROCI, Marta;INESI, ACHILLE
2011
Abstract
The gamma-butyrolactone formation by umpolung of alpha,beta-unsaturated aldehydes was catalyzed, in ionic liquids, by electrogenerated N-heterocyclic carbenes. The ionic liquids were used in the double role of pre-catalysts and solvents. (C) 2011 Elsevier B.V. All rights reserved.File allegati a questo prodotto
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