Abstract - The thermal behaviour of [Co(en)n(phen)m]Cl3 complexes has been studied using thermogravimetry (TG), differential thermogravimetry (DTG) and differential thermal analysis (DTA) in air, nitrogen and oxygen atmospheres. The effect of the stoichiometry of the complexes and that of the gas atmosphere in the furnace chamber on the thermal decomposition reaction is evidenced and discussed. The following thermal stability order has been found [Co(en)3]Cl3 [Co(en)2(phen)]Cl3 > [Co(en)(phen)2]Cl3 [Co(phen)3]Cl3
"The thermal decomposition reaction of Co(en)n(phen)m Cl3 complexes" / Bucci, Remo; Magri', Andrea; Magri', Antonio; Messina, Antonella. - In: THERMOCHIMICA ACTA. - ISSN 0040-6031. - STAMPA. - 60:3(1983), pp. 287-294. [10.1016/0040-6031(83)80250-0]
"The thermal decomposition reaction of Co(en)n(phen)m Cl3 complexes"
BUCCI, Remo;MAGRI', Andrea;MAGRI', Antonio;MESSINA, Antonella
1983
Abstract
Abstract - The thermal behaviour of [Co(en)n(phen)m]Cl3 complexes has been studied using thermogravimetry (TG), differential thermogravimetry (DTG) and differential thermal analysis (DTA) in air, nitrogen and oxygen atmospheres. The effect of the stoichiometry of the complexes and that of the gas atmosphere in the furnace chamber on the thermal decomposition reaction is evidenced and discussed. The following thermal stability order has been found [Co(en)3]Cl3 [Co(en)2(phen)]Cl3 > [Co(en)(phen)2]Cl3 [Co(phen)3]Cl3I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
