A novel efficient synthesis of N,N′-disubstituted ureas has been developed. Aromatic and aliphatic primary amines undergo oxidative carbonylation under atmospheric pressure of carbon monoxide using Pd(II) catalyst in com- bination with its anodic recycling at a graphite electrode.
Selective and Environmental Friendly Methodologies Based on the Use of Electrochemistry for Fine Chemicals Preparation: an Efficient Synthesis of N,N'-Disubstituted Ureas / Chiarotto, Isabella; Feroci, Marta. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - STAMPA. - 68:(2003), pp. 7137-7139. [10.1021/jo034750d]
Selective and Environmental Friendly Methodologies Based on the Use of Electrochemistry for Fine Chemicals Preparation: an Efficient Synthesis of N,N'-Disubstituted Ureas
CHIAROTTO, Isabella;FEROCI, Marta
2003
Abstract
A novel efficient synthesis of N,N′-disubstituted ureas has been developed. Aromatic and aliphatic primary amines undergo oxidative carbonylation under atmospheric pressure of carbon monoxide using Pd(II) catalyst in com- bination with its anodic recycling at a graphite electrode.File allegati a questo prodotto
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