The palladium-catalyzed electrocarbonylation of heteroaromatic iodides, performed in the presence of formic acid under one atmosphere of carbon monoxide, affords heteroaromatic aldehydes in moderate to good yields. It has been developed a new application of palladium-catalyzed formylation using carbon monoxide, formic acid and tertiary amines as ligands under electrochemical reducing conditions. (c) 2006 Elsevier B.V. All rights reserved.
Electrosynthesis of heteroaromatic aldehydes by palladium-catalyzed carbonylation of heteroaromatic iodides in the presence of formic acid / Chiarotto, Isabella; Feroci, Marta. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - STAMPA. - 691:11(2006), pp. 2589-2592. [10.1016/j.jorganchem.2006.01.054]
Electrosynthesis of heteroaromatic aldehydes by palladium-catalyzed carbonylation of heteroaromatic iodides in the presence of formic acid
CHIAROTTO, Isabella;FEROCI, Marta
2006
Abstract
The palladium-catalyzed electrocarbonylation of heteroaromatic iodides, performed in the presence of formic acid under one atmosphere of carbon monoxide, affords heteroaromatic aldehydes in moderate to good yields. It has been developed a new application of palladium-catalyzed formylation using carbon monoxide, formic acid and tertiary amines as ligands under electrochemical reducing conditions. (c) 2006 Elsevier B.V. All rights reserved.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
