Mantle sources of kamafugitic magmas. Insights from partial melting experiments on phlogopite clinopyroxenite and clinopyroxene glimmerite

Earth’s lithospheric mantle is dominated (usually >90% vol.%) by a nominally volatile-free mineral paragenesis with peridotitic composition. The remaining lithologies are typically hydrous and/or carbonate-bearing assemblages (the latter mostly stable at P >2 GPa), representing the products of mantle metasomatism with, or without, involvement of subduction. Despite their importance, the modal compositions of these metasomes are poorly constrained, probably containing hydrous phases (amphibole and/or phlogopite), coupled with accessory minerals, such as apatite, ilmenite, rutile and/or carbonates. These assemblages are usually considered to be the source of unusual magmas, in particular ultrapotassic compositions, especially kamafugites (K2O-rich, commonly ultracalcic, basic/ultrabasic lithologies). To evaluate if partial melting of such metasomes could effectively produce kamafugites, we performed partial melting experiments at 2.7 and 5 GPa, and 1200°C to 1550°C on clinopyroxenites variably enriched in phlogopite, olivine and accessory phases (apatite, oxides, titanite), and on a clinopyroxene glimmerite (with apatite and magnetite). At low degrees of melting, the glasses show extremely high TiO2 (<15 wt.%), CaO (<18 wt.%) and P2O5 (<7.4 wt.%), coupled with low SiO2 (>21.6 wt.%), as accessory minerals are the principal contributors in the melting reactions. Although there are no known natural counterparts for these low-degree melt compositions, they might play a key role in re-fertilisation events in the upper mantle. At increased degrees of partial melting (∼50 to ∼90%), the experimental melts approach the compositions of silica-poor, potassic/ultrapotassic and ultracalcic rocks. Indeed, experimental-produced glasses share several geochemical similarities with natural kamafugites, partially overlapping for most of the major oxides. Clinopyroxene- and phlogopite-rich lithologies, variably enriched in olivine and accessory phases (apatite, oxides, titanite) probably occur as veins pervading the lithospheric peridotitic matrix, and their partial melting, especially at high degrees, may be a plausible explanation for the genesis of SiO2-poor, K2O- and CaO-rich compositions.