Chemical condensation of layers of silicates has been often proposed as an alternative to thermal condensation, finding limited success. The formation of the industrially relevant MCM-22 zeolite (MWW IZA code) from a mild hydrothermal precursor is the most important example of 2D-3D aluminosilicate condensation. Silanols of opposed layers have been condensed by acid-driven dehydration in concentrated nitric acid, as confirmed by powder XRD and Si-29 NMR spectroscopy, implying interlayer template extraction and corresponding dealumination. Milder acid treatments favour template extraction and shrinkage of interlayer distance, but do not provide significant silanol condensation. Template extraction is further favoured by degradation of the organics in the presence of a Cu2+ homogeneous catalyst.
On the chemical condensation of the layers of zeolite precursor MCM-22(P) / Fabbiani, M; Morsli, A; Confalonieri, G; Cacciaguerra, T; Fajula, F; Haines, J; Bengueddach, A; Arletti, R; Di Renzo, F. - In: MICROPOROUS AND MESOPOROUS MATERIALS. - ISSN 1387-1811. - 332:(2022). [10.1016/j.micromeso.2021.111678]
On the chemical condensation of the layers of zeolite precursor MCM-22(P)
Confalonieri, G;
2022
Abstract
Chemical condensation of layers of silicates has been often proposed as an alternative to thermal condensation, finding limited success. The formation of the industrially relevant MCM-22 zeolite (MWW IZA code) from a mild hydrothermal precursor is the most important example of 2D-3D aluminosilicate condensation. Silanols of opposed layers have been condensed by acid-driven dehydration in concentrated nitric acid, as confirmed by powder XRD and Si-29 NMR spectroscopy, implying interlayer template extraction and corresponding dealumination. Milder acid treatments favour template extraction and shrinkage of interlayer distance, but do not provide significant silanol condensation. Template extraction is further favoured by degradation of the organics in the presence of a Cu2+ homogeneous catalyst.File | Dimensione | Formato | |
---|---|---|---|
Fabbiani_Chemical_2022.pdf
accesso aperto
Tipologia:
Versione editoriale (versione pubblicata con il layout dell'editore)
Licenza:
Creative commons
Dimensione
5.59 MB
Formato
Adobe PDF
|
5.59 MB | Adobe PDF |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.