In this communication we present a brief response to Hawthorne (2023) who, in a paper in volume 87, doi.org/10.1180/mgm.2023.8 (this journal), claims evidence for violations of the electroneutrality principle in mineral formulae derived through IMA-CNMNC procedures: i.e. the dominant-constituent rule, the valency-imposed double site-occupancy, the dominant-valency rule, and the site-total-charge approach (STC). His statement is not correct as the STC method is based on the end-member definition; thus, it cannot violate the requirements of an end-member, particularly the laws of conservation of electric charge. The STC was developed to address the shortcomings in the previous IMA-CNMNC procedures. The real question is: which method to use to define an end-member formula? Currently, there are two approaches: (1) STC, which first identifies the dominant end-member charge arrangement and then leads to the dominant end-member composition; (2) the dominant end-member approach.

A brief comment on Hawthorne (2023).: "On the definition of distinct mineral species. A critique of current IMA-CNMNC procedures" / Bosi, F.; Hatert, F.; Pasero, M.; Mills, S. J.; Miyawaki, R.; Halenius, U.. - In: MINERALOGICAL MAGAZINE. - ISSN 0026-461X. - 87:3(2023), pp. 505-507. [10.1180/mgm.2023.33]

A brief comment on Hawthorne (2023).: "On the definition of distinct mineral species. A critique of current IMA-CNMNC procedures"

Bosi F.
;
2023

Abstract

In this communication we present a brief response to Hawthorne (2023) who, in a paper in volume 87, doi.org/10.1180/mgm.2023.8 (this journal), claims evidence for violations of the electroneutrality principle in mineral formulae derived through IMA-CNMNC procedures: i.e. the dominant-constituent rule, the valency-imposed double site-occupancy, the dominant-valency rule, and the site-total-charge approach (STC). His statement is not correct as the STC method is based on the end-member definition; thus, it cannot violate the requirements of an end-member, particularly the laws of conservation of electric charge. The STC was developed to address the shortcomings in the previous IMA-CNMNC procedures. The real question is: which method to use to define an end-member formula? Currently, there are two approaches: (1) STC, which first identifies the dominant end-member charge arrangement and then leads to the dominant end-member composition; (2) the dominant end-member approach.
2023
end-member; IMA-CNMNC; mineral formula; site total charge
01 Pubblicazione su rivista::01b Commento, Erratum, Replica e simili
A brief comment on Hawthorne (2023).: "On the definition of distinct mineral species. A critique of current IMA-CNMNC procedures" / Bosi, F.; Hatert, F.; Pasero, M.; Mills, S. J.; Miyawaki, R.; Halenius, U.. - In: MINERALOGICAL MAGAZINE. - ISSN 0026-461X. - 87:3(2023), pp. 505-507. [10.1180/mgm.2023.33]
File allegati a questo prodotto
File Dimensione Formato  
Bosi_Brief_2023.pdf

solo gestori archivio

Note: 2023 Commnet on Hawthorne MM
Tipologia: Versione editoriale (versione pubblicata con il layout dell'editore)
Licenza: Tutti i diritti riservati (All rights reserved)
Dimensione 89.52 kB
Formato Adobe PDF
89.52 kB Adobe PDF   Contatta l'autore

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/1699421
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 1
  • ???jsp.display-item.citation.isi??? 1
social impact