In the present work we report the full structural and spectroscopic characterization of an UICC amosite (fibrous gnmerite) standard sample from Penge mine (South Africa). The chemical composition was obtained by SEM-EDS and cation site partition was retrieved by complementing chemical, Mossbauer and X-ray powder diffraction data. Cell parameters, fractional coordinates, and site scattering for M(1), M(2), M(3), M(4) were refined using the Rietveld method. The retrieved crystal chemical formula (A)[Na-0.02](Sigma 0.02)(B)(Fe1.542+Mn0.29Na0.10Ca0.07)Sigma(C)(2.00)(Fe2.922+Mg1.93Fe0.153+)(Sigma 5.00)(T)(Si7.93Al0.07)(Sigma 8.00) O-22.00 (W)(OH2.00)(Sigma 2.00) is in reasonable agreement with reference data.Rietveld refinement results evidenced that Fe2+ is allocated in the octahedral layer following the site preferencesM(1)approximate to M(3)>M(2), whereas Mg preferentially is ordered at M(2). Refined cell parameters are: a=9.55264(17) angstrom, b=18.3069(3) angstrom, c=5.33487(8) angstrom, beta= 101 .840(3)degrees, V=913.11(3) angstrom(3). Quantitative Phase Analysis indicates about 10 wt.% of accessory phases including quartz, ankerite and minor stilpnomelane and biotite/annite. Obtained results are the basis for further studies aimed at investigating possible correlation between physico-chemical features of the fibres and their chemical reactivity and toxicity.
Chemical and structural characterization of UICC amosite fibres from Penge mine (South Africa) / Ballirano, Paolo; Skogby, Henrik; Gianchiglia, Flaminia; DI CARLO, MARIA CRISTINA; Campopiano, Antonella; Cannizzaro, Annapaola; Olori, Angelo; Pacella, Alessandro. - In: PERIODICO DI MINERALOGIA. - ISSN 0369-8963. - 91:2(2022), pp. 143-154. [10.13133/2239-1002/17767]
Chemical and structural characterization of UICC amosite fibres from Penge mine (South Africa)
Paolo Ballirano;Flaminia Gianchiglia;Maria Cristina Di Carlo;Alessandro Pacella
2022
Abstract
In the present work we report the full structural and spectroscopic characterization of an UICC amosite (fibrous gnmerite) standard sample from Penge mine (South Africa). The chemical composition was obtained by SEM-EDS and cation site partition was retrieved by complementing chemical, Mossbauer and X-ray powder diffraction data. Cell parameters, fractional coordinates, and site scattering for M(1), M(2), M(3), M(4) were refined using the Rietveld method. The retrieved crystal chemical formula (A)[Na-0.02](Sigma 0.02)(B)(Fe1.542+Mn0.29Na0.10Ca0.07)Sigma(C)(2.00)(Fe2.922+Mg1.93Fe0.153+)(Sigma 5.00)(T)(Si7.93Al0.07)(Sigma 8.00) O-22.00 (W)(OH2.00)(Sigma 2.00) is in reasonable agreement with reference data.Rietveld refinement results evidenced that Fe2+ is allocated in the octahedral layer following the site preferencesM(1)approximate to M(3)>M(2), whereas Mg preferentially is ordered at M(2). Refined cell parameters are: a=9.55264(17) angstrom, b=18.3069(3) angstrom, c=5.33487(8) angstrom, beta= 101 .840(3)degrees, V=913.11(3) angstrom(3). Quantitative Phase Analysis indicates about 10 wt.% of accessory phases including quartz, ankerite and minor stilpnomelane and biotite/annite. Obtained results are the basis for further studies aimed at investigating possible correlation between physico-chemical features of the fibres and their chemical reactivity and toxicity.File | Dimensione | Formato | |
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