In a recent Science paper, Stahl and co-workers describe direct C(sp3)−H methylation via Ni-catalyzed cross-coupling of a radical pair deriving from divergent hydrogen atom transfer (HAT) and C–Me cleavage pathways in a photogenerated alkoxyl radical. The implications of these findings for the rapidly expanding field of C−H methylation are discussed.
Aliphatic C–H bond methylation enabled by hydrogen atom transfer / Olivo, Giorgio; Bietti, Massimo. - In: CHEM. - ISSN 2451-9294. - 7:6(2021), pp. 1427-1430. [10.1016/j.chempr.2021.05.016]
Aliphatic C–H bond methylation enabled by hydrogen atom transfer
Olivo, Giorgio
Primo
;Bietti, Massimo
Ultimo
2021
Abstract
In a recent Science paper, Stahl and co-workers describe direct C(sp3)−H methylation via Ni-catalyzed cross-coupling of a radical pair deriving from divergent hydrogen atom transfer (HAT) and C–Me cleavage pathways in a photogenerated alkoxyl radical. The implications of these findings for the rapidly expanding field of C−H methylation are discussed.File allegati a questo prodotto
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