Aerosol optical characteristics in the urban area of Rome, Italy, and their impact on the UV index

The aerosol optical characteristics in the urban area of Rome were retrieved over a period of 7 years from March to September 2010–2016. The impact of aerosol single scattering albedo (SSA), optical depth (AOD), estimated at 400 nm, and Ångström exponent on the ultraviolet (UV) index has been analyzed. Aerosol optical properties are provided by a PREDE-POM sun-sky radiometer of the ESR/SKYNET network and the UV index values were retrieved by a Brewer spectrophotometer both located in Rome. Chemical characterization of urban PM10 (particulate matter 10 micrometers or less in diameter) samples, collected during the URBan Sustainability Related to Observed and Monitored Aerosol (URBS ROMA) intensive filed campaign held in summer 2011 in the same site, was performed. PM macro-components were grouped in order to evaluate the contribution of the main macro-sources (SOIL, SEA, SECONDARY INORGANIC, ORGANICS and TRAFFIC) and the analysis of the modulation of their concentration was found to strongly affects the absorption capability of the atmosphere over Rome. The surface forcing efficiency, provided by the decreasing trend of UV index with AOD, which is the primary parameter affecting the surface irradiance, was found very significant, probably masking the dependence of UV index on SSA and Ångström exponents. Moreover it was found greater for larger particles and with a more pronounced slope at the smaller solar zenith angle. In Rome large particles are generally less absorbing since related to the presence of SOIL and SEA components in the atmosphere. The former contribution was found much higher in summer months because of the numerous episodes of Saharan dust transport.