Cyclic voltammetry provides the first direct evidence of N-heterocyclic carbene (NHC) presence in neat 1-‐butyl-3-methylimidazolium acetate ionic liquid (BMImAcO) at 120°C. The NHC existence, proved by its oxidation current in cyclic voltammetry, was confirmed by the formation of a PhCHO-NHC adduct in pure ionic liquid. The role of the temperature was considered.
First direct evidence of N-heterocyclic carbene in BMIm acetate ionic liquid. An electrochemical and chemical study on the role of temperature / Chiarotto, I.; Feroci, M.; Inesi, A.. - In: NEW JOURNAL OF CHEMISTRY. - ISSN 1144-0546. - STAMPA. - 41:(2017), pp. 7840-7843. [10.1039/C7NJ00779E]
First direct evidence of N-heterocyclic carbene in BMIm acetate ionic liquid. An electrochemical and chemical study on the role of temperature
I. Chiarotto
;M. Feroci;A. Inesi
2017
Abstract
Cyclic voltammetry provides the first direct evidence of N-heterocyclic carbene (NHC) presence in neat 1-‐butyl-3-methylimidazolium acetate ionic liquid (BMImAcO) at 120°C. The NHC existence, proved by its oxidation current in cyclic voltammetry, was confirmed by the formation of a PhCHO-NHC adduct in pure ionic liquid. The role of the temperature was considered.| File | Dimensione | Formato | |
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NJCAccepted.pdf
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NJC Accepted.pdf
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