Two-phase water model in the cellulose network of paper

Abstract Waterdiffusionincellulosewasstudiedviatwo-phaseK ̈argermodel and the propagator method. In addition to ruling out anomalous diffusion, the mean squared displacements obtained at different diffusion times from the K ̈arger model allowed to characterize the system’s phases by their aver- age confining sizes, average connectivity and average apparent diffusion co- efficients. The two-phase scheme was confirmed by the propagator method, which has given insights into the confining phase-geometry, found consistent with a parallel-plane arrangement. Final results indicate that water in cellu- lose is confined in two different types of amorphous domains, one placed at fiber surfaces, the other at fiber cores. This picture fully corresponds to the phenomenological categories so far used to identify water in cellulose fibers, namely, free and bound water, or freezing and non-freezing water.