our catalysts mimic the behavior of a metalloenzyme, in that they bind 2-cyclopenten-1-one and promote reaction of the bound substrate. Release of the addition product, followed by preferential binding to another enone molecule, ensures the onset of a catalytic cycle with high turnover efficiency.
"Supramolecular Catalysis of 1,4-Thiol Addition by Salophen-Uranyl Complexes" / VAN AXEL CASTELLI, V.; DALLA CORT, Antonella; Mandolini, Luigi; Reinhdout, D. N.. - In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. - ISSN 0002-7863. - STAMPA. - 120:(1998), pp. 12688-12689. [10.1021/ja9819920]
"Supramolecular Catalysis of 1,4-Thiol Addition by Salophen-Uranyl Complexes"
DALLA CORT, Antonella;MANDOLINI, Luigi;
1998
Abstract
our catalysts mimic the behavior of a metalloenzyme, in that they bind 2-cyclopenten-1-one and promote reaction of the bound substrate. Release of the addition product, followed by preferential binding to another enone molecule, ensures the onset of a catalytic cycle with high turnover efficiency.File allegati a questo prodotto
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