(±)-[5-13C]Faktor-1 ester is synthesized following an east-west disconnection strategy and is used to show by specific enzymic incorporation experiments that the first C-methylation product, precorrin-1, on the B12 biosynthetic pathway is a tetrahydrochlorin.
Biosynthesis of vitamin B12: synthesis of (±)-[5-13C]Faktor-1 ester: determination of the oxidation state of precorrin-1 / R. D., Brunt; F. J., Leeper; Grgurina, Ingeborg; A. R., Battersby. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - STAMPA. - 7:(1989), pp. 428-431. [10.1039/c39890000428]
Biosynthesis of vitamin B12: synthesis of (±)-[5-13C]Faktor-1 ester: determination of the oxidation state of precorrin-1
GRGURINA, Ingeborg;
1989
Abstract
(±)-[5-13C]Faktor-1 ester is synthesized following an east-west disconnection strategy and is used to show by specific enzymic incorporation experiments that the first C-methylation product, precorrin-1, on the B12 biosynthetic pathway is a tetrahydrochlorin.File allegati a questo prodotto
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