We investigate a kinetic heat engine model composed of particles enclosed in a box where one side acts as a thermostat and the opposite side is a piston exerting a given pressure. Pressure and temperature are varied in a cyclical protocol of period \tau: their relative excursions, \delta and \epsilon, respectively, constitute the thermodynamic forces dragging the system out of equilibrium. The analysis of the entropy production of the system allows us to define the conjugated fluxes, which are proportional to the extracted work and the consumed heat. In the limit of small \delta, and \epsilon the fluxes are linear in the forces through a \tau-dependent Onsager matrix whose off-diagonal elements satisfy a reciprocal relation. The dynamics of the piston can be approximated, through a coarse-graining procedure, by a Klein-Kramers equation which—in the linear regime—yields analytic expressions for the Onsager coefficients and the entropy production. A study of the efficiency at maximum power shows that the Curzon-Ahlborn formula is always an upper limit which is approached at increasing values of the thermodynamic forces, i.e., outside of the linear regime. In all our analysis the adiabatic limit \tau\to\infty and the the small-force limit \delta, \epsilon\to 0 are not directly related.v

Linear and nonlinear thermodynamics of a kinetic heat engine with fast transformations / Cerino, Luca; Puglisi, Andrea; Vulpiani, Angelo. - In: PHYSICAL REVIEW. E. - ISSN 2470-0045. - STAMPA. - 93:(2016), p. 042116. [https://doi.org/10.1103/PhysRevE.93.042116]

Linear and nonlinear thermodynamics of a kinetic heat engine with fast transformations

CERINO , LUCA;PUGLISI, Andrea;VULPIANI, Angelo
2016

Abstract

We investigate a kinetic heat engine model composed of particles enclosed in a box where one side acts as a thermostat and the opposite side is a piston exerting a given pressure. Pressure and temperature are varied in a cyclical protocol of period \tau: their relative excursions, \delta and \epsilon, respectively, constitute the thermodynamic forces dragging the system out of equilibrium. The analysis of the entropy production of the system allows us to define the conjugated fluxes, which are proportional to the extracted work and the consumed heat. In the limit of small \delta, and \epsilon the fluxes are linear in the forces through a \tau-dependent Onsager matrix whose off-diagonal elements satisfy a reciprocal relation. The dynamics of the piston can be approximated, through a coarse-graining procedure, by a Klein-Kramers equation which—in the linear regime—yields analytic expressions for the Onsager coefficients and the entropy production. A study of the efficiency at maximum power shows that the Curzon-Ahlborn formula is always an upper limit which is approached at increasing values of the thermodynamic forces, i.e., outside of the linear regime. In all our analysis the adiabatic limit \tau\to\infty and the the small-force limit \delta, \epsilon\to 0 are not directly related.v
2016
thermodynamics, small, system, statistical mechanics, nonequilibrium, engines, efficeincy, power
01 Pubblicazione su rivista::01a Articolo in rivista
Linear and nonlinear thermodynamics of a kinetic heat engine with fast transformations / Cerino, Luca; Puglisi, Andrea; Vulpiani, Angelo. - In: PHYSICAL REVIEW. E. - ISSN 2470-0045. - STAMPA. - 93:(2016), p. 042116. [https://doi.org/10.1103/PhysRevE.93.042116]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/931864
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