(Ethoxycarbonyl)nitrene (NCO2Et) adds selectively to methyl neryl ether, geranyl methyl ether, and allyl neryl ether. For all the substrates the main product (up to 50%) is the aziridine deriving from addition to the double bond remote from the oxygen atom. Competition experiments point to a different reactivity of the two kind of double bonds and these results are compared with those reported for similar substrates in other addition reactions.
REGIOSELECTIVE AMINATION OF POLYUNSATURATED ETHERS / Giorgio, Cerichelli; Alessandro, Freddi; Loreto, Maria Antonietta; Pellacani, Lucio; Tardella, Paolo Antonio. - In: TETRAHEDRON. - ISSN 0040-4020. - STAMPA. - 48:12(1992), pp. 2495-2500. [10.1016/s0040-4020(01)88768-8]
REGIOSELECTIVE AMINATION OF POLYUNSATURATED ETHERS
LORETO, Maria Antonietta;PELLACANI, Lucio;TARDELLA, Paolo Antonio
1992
Abstract
(Ethoxycarbonyl)nitrene (NCO2Et) adds selectively to methyl neryl ether, geranyl methyl ether, and allyl neryl ether. For all the substrates the main product (up to 50%) is the aziridine deriving from addition to the double bond remote from the oxygen atom. Competition experiments point to a different reactivity of the two kind of double bonds and these results are compared with those reported for similar substrates in other addition reactions.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
