Functionalised (allenylmethyl)silanes react with chlorosulphonyl isocyanate in a highly regioselective manner to provide beta-lactams with the side-chain functionality of the asparenomycins. Chirally enriched (allenylmethyl)silanes transfer their axial chirality to the carbon-centred chirality in the product beta-lactams.
BETA-LACTAMS FROM CHIRALLY-ENRICHED (ALLENYLMETHYL)SILANES / E. W., Colvin; W. A., Konig; Loreto, Maria Antonietta; J. Y., Rowden; I., Tommasini. - In: BIOORGANIC & MEDICINAL CHEMISTRY LETTERS. - ISSN 0960-894X. - STAMPA. - 3:11(1993), pp. 2405-2408. [10.1016/s0960-894x(01)80965-3]
BETA-LACTAMS FROM CHIRALLY-ENRICHED (ALLENYLMETHYL)SILANES
LORETO, Maria Antonietta;
1993
Abstract
Functionalised (allenylmethyl)silanes react with chlorosulphonyl isocyanate in a highly regioselective manner to provide beta-lactams with the side-chain functionality of the asparenomycins. Chirally enriched (allenylmethyl)silanes transfer their axial chirality to the carbon-centred chirality in the product beta-lactams.File allegati a questo prodotto
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