The palladium-catalyzed reaction of propargylic carbonates with Meldrum’s acid derivatives proceeds smoothly in the presence of Pd(OAc)2 and P(2-furyl)3 in THF at 80 °C to give substitution products. The substitution products can be useful intermediates for the stereoselective synthesis of functionalized (Z)-γ-alkylidene-γ-butyrolactones

Palladium-catalyzed nucleophilic substitution of propargylic carbonates and meldrum's acid derivatives / Ambrogio, Ilaria; Cacchi, Sandro; Fabrizi, Giancarlo; Goggiamani, Antonella; Iazzetti, Antonia. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - 2015:14(2015), pp. 3147-3151. [10.1002/ejoc.201500337]

Palladium-catalyzed nucleophilic substitution of propargylic carbonates and meldrum's acid derivatives

CACCHI, Sandro;FABRIZI, Giancarlo;GOGGIAMANI, ANTONELLA
;
IAZZETTI, Antonia
2015

Abstract

The palladium-catalyzed reaction of propargylic carbonates with Meldrum’s acid derivatives proceeds smoothly in the presence of Pd(OAc)2 and P(2-furyl)3 in THF at 80 °C to give substitution products. The substitution products can be useful intermediates for the stereoselective synthesis of functionalized (Z)-γ-alkylidene-γ-butyrolactones
alkynes; homogeneous catalysis; nucleophilic substitution; palladium; organic chemistry; physical and theoretical chemistry
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Palladium-catalyzed nucleophilic substitution of propargylic carbonates and meldrum's acid derivatives / Ambrogio, Ilaria; Cacchi, Sandro; Fabrizi, Giancarlo; Goggiamani, Antonella; Iazzetti, Antonia. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - 2015:14(2015), pp. 3147-3151. [10.1002/ejoc.201500337]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/867570
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