The atroposelective desymmetrization of N-arylmaleimides was realized by means of a primary amine catalyzed Diels−Alder reaction of enones. The chiral axis as new element of chirality is generated under the remote control of the catalyst that selectively drives the formal Diels−Alder reaction through an exclusive stereochemical outcome.
Organocatalytic atroposelective formal Diels-Alder desymmetrization of N -arylmaleimides / Eudier, Florine; Righi, Paolo; Mazzanti, Andrea; Ciogli, Alessia; Bencivenni, Giorgio. - In: ORGANIC LETTERS. - ISSN 1523-7052. - STAMPA. - 17:7(2015), pp. 1728-1731. [10.1021/acs.orglett.5b00509]
Organocatalytic atroposelective formal Diels-Alder desymmetrization of N -arylmaleimides
CIOGLI, Alessia;
2015
Abstract
The atroposelective desymmetrization of N-arylmaleimides was realized by means of a primary amine catalyzed Diels−Alder reaction of enones. The chiral axis as new element of chirality is generated under the remote control of the catalyst that selectively drives the formal Diels−Alder reaction through an exclusive stereochemical outcome.| File | Dimensione | Formato | |
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