We show that the presence and the location of first order phase transitions in a thermodynamic system can be deduced by the study of the topology of the potential energy function, V (q), without introducing any thermodynamic measure. In particular, we present the thermodynamics of an analytically solvable mean-field model with a k-body interaction which -depending on the value of k- displays no transition (k=1), second order (k=2) or first order (k>2) phase transition. This rich behavior is quantitatively retrieved by the investigation of a topological invariant, the Euler characteristic χ(v), of some submanifolds of the configuration space. Finally, we conjecture a direct link between χ(v) and the thermodynamic entropy.

Topological signature of first order phase transitions in a mean field model / Angelani, L.; Casetti, L.; Pettini, M.; Ruocco, Giancarlo; Zamponi, F.. - In: EUROPHYSICS LETTERS. - ISSN 0295-5075. - 62:(2003), p. 775.

Topological signature of first order phase transitions in a mean field model

RUOCCO, Giancarlo;F. ZAMPONI
2003

Abstract

We show that the presence and the location of first order phase transitions in a thermodynamic system can be deduced by the study of the topology of the potential energy function, V (q), without introducing any thermodynamic measure. In particular, we present the thermodynamics of an analytically solvable mean-field model with a k-body interaction which -depending on the value of k- displays no transition (k=1), second order (k=2) or first order (k>2) phase transition. This rich behavior is quantitatively retrieved by the investigation of a topological invariant, the Euler characteristic χ(v), of some submanifolds of the configuration space. Finally, we conjecture a direct link between χ(v) and the thermodynamic entropy.
2003
Topology; phase transitions; statistical mechanics
01 Pubblicazione su rivista::01a Articolo in rivista
Topological signature of first order phase transitions in a mean field model / Angelani, L.; Casetti, L.; Pettini, M.; Ruocco, Giancarlo; Zamponi, F.. - In: EUROPHYSICS LETTERS. - ISSN 0295-5075. - 62:(2003), p. 775.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/83122
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