Polymer-Surfactant Interactions

Aqueous solutions containing poly(vinyl-pyrrolidone) and sodium caprylate, or poly(vinyl-pyrrolidone) and tetraethylammonium perfluorooctanesulfonate, respectively, have been investigated by volumetric, ionic conductivity and surface tension methods. The presence of an interaction region has been determined from conductivity and surface tension. The width of such a region depends on the amount of polymer in the mixture, temperature, surfactant content and added electrolyte (NaCl). The observed behaviour was explained in terms of the combined effects played by the alkyl-chain hydophobicity, polar head group(s) and counter-ions. An approximate solution to a mass action model for the binding of surfactants onto polymers has been introduced. It allows determining the width of the interaction region as a function of polymer mass percent in the mixture.