Here we report the synthesis at low temperature (220 °C) by a solvothermal method of highly crystalline LiCoPO4. This material is a candidate for application as cathode in next-generation Li-ion cells. The presented synthetic route allows a careful tailoring of the sample morphology and leads to morphologically homogeneous platelet-like particles. The obtained material has been characterized by synchrotron radiation X-ray diffraction, vibrational spectroscopies, X-ray photoemission spectroscopy and electron microscopies. The synthesized material has been also characterized in lithium cells to highlight its ability to reversibly cycle lithium.

Controlled synthesis of LiCoPO4 by a solvo-thermal method at 220 °C / S., Brutti; J., Manzi; A., De Bonis; DI LECCE, Daniele; Vitucci, FRANCESCO MARIA; Paolone, Annalisa; Trequattrini, Francesco; Panero, Stefania. - In: MATERIALS LETTERS. - ISSN 0167-577X. - STAMPA. - 145:(2015), pp. 324-327. [10.1016/j.matlet.2015.01.137]

Controlled synthesis of LiCoPO4 by a solvo-thermal method at 220 °C

S. Brutti;DI LECCE, DANIELE;VITUCCI, FRANCESCO MARIA;PAOLONE, Annalisa;TREQUATTRINI, Francesco;PANERO, Stefania
2015

Abstract

Here we report the synthesis at low temperature (220 °C) by a solvothermal method of highly crystalline LiCoPO4. This material is a candidate for application as cathode in next-generation Li-ion cells. The presented synthetic route allows a careful tailoring of the sample morphology and leads to morphologically homogeneous platelet-like particles. The obtained material has been characterized by synchrotron radiation X-ray diffraction, vibrational spectroscopies, X-ray photoemission spectroscopy and electron microscopies. The synthesized material has been also characterized in lithium cells to highlight its ability to reversibly cycle lithium.
2015
LiCoPO4, Li-ion cells, FTIR, XPS, X-ray techniques, Crystal growth, Energy storage and conversion
01 Pubblicazione su rivista::01a Articolo in rivista
Controlled synthesis of LiCoPO4 by a solvo-thermal method at 220 °C / S., Brutti; J., Manzi; A., De Bonis; DI LECCE, Daniele; Vitucci, FRANCESCO MARIA; Paolone, Annalisa; Trequattrini, Francesco; Panero, Stefania. - In: MATERIALS LETTERS. - ISSN 0167-577X. - STAMPA. - 145:(2015), pp. 324-327. [10.1016/j.matlet.2015.01.137]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/772182
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