In this work we report the characteristics of a lithium ion battery formed by the combination of a Fe-substituted, C-coated LiCoPO4 cathode with a nano-structured Sn-C anode in a N-butyl-N-methylpyrrolidinium-bis(trifluoromethanesulfonyl)-Imide (Pyr14TFSI)-LiTFSI non-flammable, IL-based electrolyte. The preliminary results show that the cell operates at about 4.5 V, as a result of the electrochemical insertion-deinsertion process due to Co3+/Co2+ redox couple at the cathode and Li-Sn-C alloying/de-alloying process at the anode, with a specific capacity approaching 90 mAh g-1.
A new Sn-C/LiFe0.1Co0.9PO4 full lithium-ion cell with ionic liquid-based electrolyte / DI LECCE, Daniele; Brutti, S.; Panero, Stefania; Hassoun, Jusef. - In: MATERIALS LETTERS. - ISSN 0167-577X. - ELETTRONICO. - 139:(2015), pp. 329-332. [10.1016/j.matlet.2014.10.089]
A new Sn-C/LiFe0.1Co0.9PO4 full lithium-ion cell with ionic liquid-based electrolyte
DI LECCE, DANIELE;S. Brutti;PANERO, Stefania;HASSOUN, JUSEF
2015
Abstract
In this work we report the characteristics of a lithium ion battery formed by the combination of a Fe-substituted, C-coated LiCoPO4 cathode with a nano-structured Sn-C anode in a N-butyl-N-methylpyrrolidinium-bis(trifluoromethanesulfonyl)-Imide (Pyr14TFSI)-LiTFSI non-flammable, IL-based electrolyte. The preliminary results show that the cell operates at about 4.5 V, as a result of the electrochemical insertion-deinsertion process due to Co3+/Co2+ redox couple at the cathode and Li-Sn-C alloying/de-alloying process at the anode, with a specific capacity approaching 90 mAh g-1.| File | Dimensione | Formato | |
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