This paper deals with gold extraction from a refractory concentrate by chlorine leaching. The process considers a pre-treatment of refractory materials by low temperature oxidation carried out with low oxygen concentration. The oxidized material is treated by leaching with brine. After gold adsorption/reduction onto activated carbon, iron and base metals can be precipitated by NaOH. Roasting tests show the necessity to carry out a thermal pre-treatment at least at 550 C to obtain a reduction of sulfur and mercury in the material (50% and 90%, respectively). Highest gold extraction yield (around 93%) is obtained in the leaching test performed with material sample treated at 650 C. This result confirms the necessity to optimize the thermal pre-treatment to improve Au recovery and to reduce chlorine consumption. A comparison with conventional cyanidation confirms that chlorination could be an useful alternative: in fact, gold extraction yield is quite low: 57% in non-pre-treated material and 25% in pre-treatment material. © 2013 Published by Elsevier B.V. on behalf of China University of Mining & Technology.
Roasting and chlorine leaching of gold-bearing refractory concentrate: Experimental and process analysis / DE MICHELIS, Ida; Agostino, Olivieri; Stefano, Ubaldini; Francesco, Ferella; Francesca, Beolchini; Francesco, Vegliò. - In: INTERNATIONAL JOURNAL OF MINING SCIENCE AND TECHNOLOGY. - ISSN 2095-2686. - STAMPA. - 23:(2013), pp. 709-715. [10.1016/j.ijmst.2013.08.015]
Roasting and chlorine leaching of gold-bearing refractory concentrate: Experimental and process analysis
DE MICHELIS, IDA;
2013
Abstract
This paper deals with gold extraction from a refractory concentrate by chlorine leaching. The process considers a pre-treatment of refractory materials by low temperature oxidation carried out with low oxygen concentration. The oxidized material is treated by leaching with brine. After gold adsorption/reduction onto activated carbon, iron and base metals can be precipitated by NaOH. Roasting tests show the necessity to carry out a thermal pre-treatment at least at 550 C to obtain a reduction of sulfur and mercury in the material (50% and 90%, respectively). Highest gold extraction yield (around 93%) is obtained in the leaching test performed with material sample treated at 650 C. This result confirms the necessity to optimize the thermal pre-treatment to improve Au recovery and to reduce chlorine consumption. A comparison with conventional cyanidation confirms that chlorination could be an useful alternative: in fact, gold extraction yield is quite low: 57% in non-pre-treated material and 25% in pre-treatment material. © 2013 Published by Elsevier B.V. on behalf of China University of Mining & Technology.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.