The structure modifications induced by electrogenerated superoxide ion in 4-substituted cyclohexanones are related to the reactivity of O2 - as base, and electron-donor. The formation of dicarboxylic acids (50-70% yield, after 8 F per mole of substrate had flowed) implies the participation of unreduced O2. Redox cycles involving O2/O2 - , O2/O2H. and ketone/alcohol systems may be considered as an hypothesis.
Reactivity of electrogenerated superoxide ion. Part 3. Oxidative cleavage and reduction of some cyclohexanones / Curulli, A.; Feroci, Marta; Inesi, Achille. - In: JOURNAL OF CHEMICAL RESEARCH. SYNOPSES. - ISSN 0308-2342. - STAMPA. - (1993), pp. 448-449.
Reactivity of electrogenerated superoxide ion. Part 3. Oxidative cleavage and reduction of some cyclohexanones
FEROCI, Marta;INESI, ACHILLE
1993
Abstract
The structure modifications induced by electrogenerated superoxide ion in 4-substituted cyclohexanones are related to the reactivity of O2 - as base, and electron-donor. The formation of dicarboxylic acids (50-70% yield, after 8 F per mole of substrate had flowed) implies the participation of unreduced O2. Redox cycles involving O2/O2 - , O2/O2H. and ketone/alcohol systems may be considered as an hypothesis.| File | Dimensione | Formato | |
|---|---|---|---|
|
1. J Chem Res, 1993,488-489.pdf
solo gestori archivio
Tipologia:
Versione editoriale (versione pubblicata con il layout dell'editore)
Licenza:
Creative commons
Dimensione
3 MB
Formato
Adobe PDF
|
3 MB | Adobe PDF | Contatta l'autore |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
