Gaseous ions: A variant of IR spectroscopy, developed to solve the structure of gaseous ions, was applied to the prototypical silyl-substituted arenium ion, [H3Si-C6H6]+. The experimental IR multiphoton-induced dissociation (IRMPD) spectrum is found to match the IR absorption features calculated for the ipsoprotonated species (see figure). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
Infrared spectroscopy of protonated phenylsilane in the gas phase / Chiavarino, Barbara; Crestoni, Maria Elisa; Fornarini, Simonetta; Jo�l, Lemaire; L., Mac Aleese; P., Maitre. - In: CHEMPHYSCHEM. - ISSN 1439-4235. - STAMPA. - 6:3(2005), pp. 437-440. [10.1002/cphc.200400511]
Infrared spectroscopy of protonated phenylsilane in the gas phase
CHIAVARINO, Barbara;CRESTONI, Maria Elisa;FORNARINI, Simonetta;
2005
Abstract
Gaseous ions: A variant of IR spectroscopy, developed to solve the structure of gaseous ions, was applied to the prototypical silyl-substituted arenium ion, [H3Si-C6H6]+. The experimental IR multiphoton-induced dissociation (IRMPD) spectrum is found to match the IR absorption features calculated for the ipsoprotonated species (see figure). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.