The structural properties of a mixture of ethylammonium nitrate (EAN), a protic ionic liquid, and lithium nitrate are explored using X-ray diffraction and reverse Monte Carlo simulation. The system is characterised by the amphiphilically driven polar-apolar domains segregation that is peculiar of EAN, whilst the lithium ions distribute in the charged domains where they undergo a further level of self-segregation, prompting for a new ion solvation mechanism in amphiphilically nanostructured ionic liquids. © 2014 Elsevier B.V. All rights reserved.
How does lithium nitrate dissolve in a protic ionic liquid? / Russina, Olga; Caminiti, Ruggero; Méndez Morales, Trinidad; Carrete, Jesùs; Cabeza, Oscar; Gallego, Luis Javier; Varela, Luis M.; Triolo, Alessandro. - In: JOURNAL OF MOLECULAR LIQUIDS. - ISSN 0167-7322. - ELETTRONICO. - 205:(2015), pp. 16-21. [10.1016/j.molliq.2014.08.007]
How does lithium nitrate dissolve in a protic ionic liquid?
Russina, Olga;Caminiti, Ruggero;
2015
Abstract
The structural properties of a mixture of ethylammonium nitrate (EAN), a protic ionic liquid, and lithium nitrate are explored using X-ray diffraction and reverse Monte Carlo simulation. The system is characterised by the amphiphilically driven polar-apolar domains segregation that is peculiar of EAN, whilst the lithium ions distribute in the charged domains where they undergo a further level of self-segregation, prompting for a new ion solvation mechanism in amphiphilically nanostructured ionic liquids. © 2014 Elsevier B.V. All rights reserved.| File | Dimensione | Formato | |
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