The tendency of histidine to form biologically important complexes with transition metal ions is well known. However, in the literature there is little information about the thermochemical behaviour of these complexes in the solid state, and the results are often contradictory. In this work, the synthesis and the thermoanalytical investigation of complexes of formula MeHis(2), MeHis(2)(NO3)(2) and MeHis(2)(NO3)(2) are reported, with Me = Co(II), Ni(II) or Cu(II) and His = histidine.
Thermoanalytical behaviour of histidine complexes with transition metal ions / Materazzi, Stefano; Curini, R.; D'Ascenzo, G.. - In: THERMOCHIMICA ACTA. - ISSN 0040-6031. - STAMPA. - 275:1(1996), pp. 93-108. [10.1016/0040-6031(95)02718-1]
Thermoanalytical behaviour of histidine complexes with transition metal ions
MATERAZZI, Stefano;R. CURINI;
1996
Abstract
The tendency of histidine to form biologically important complexes with transition metal ions is well known. However, in the literature there is little information about the thermochemical behaviour of these complexes in the solid state, and the results are often contradictory. In this work, the synthesis and the thermoanalytical investigation of complexes of formula MeHis(2), MeHis(2)(NO3)(2) and MeHis(2)(NO3)(2) are reported, with Me = Co(II), Ni(II) or Cu(II) and His = histidine.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
