The dynamics of the radical–radical reaction O(3P)+C3H5 has been investigated by means of the crossed molecular beam technique with mass spectrometric detection at a collision energy of 73.0 kJ mol1; the reaction mechanism of the H-displacement channel has been elucidated, while experimental evidence of the occurrence of one or more C–C bond-breaking channels at this collision energy has been obtained.
Crossed beam studies of radical-radical reactions: O(3P)+C3H5 (allyl) / Leonori, F; Balucani, N; Capozza, G; Segoloni, E; Stranges, Domenico; Casavecchia, P.. - In: PHYSICAL CHEMISTRY CHEMICAL PHYSICS. - ISSN 1463-9076. - STAMPA. - 9:(2007), pp. 1307-1311. [10.1039/b618971g]
Crossed beam studies of radical-radical reactions: O(3P)+C3H5 (allyl)
STRANGES, Domenico;
2007
Abstract
The dynamics of the radical–radical reaction O(3P)+C3H5 has been investigated by means of the crossed molecular beam technique with mass spectrometric detection at a collision energy of 73.0 kJ mol1; the reaction mechanism of the H-displacement channel has been elucidated, while experimental evidence of the occurrence of one or more C–C bond-breaking channels at this collision energy has been obtained.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
