This contribution summarize our recent work devoted to detect and thermochemically characterise by KEMS experiments (Knudsen Effusion Mass Spectrometry) a number of diatomic gaseous molecules either never observed before or whose bond energy was unknown. The results obtained over the years for the intragroup 14 and the group 11-group 2 species are here collected and compared with quantum chemical calculations at the CCSD(T) level. © The Electrochemical Society.
Determination of the dissociation energy of Diatomic Molecules by KEMS (Knudsen Effusion Mass Spectrometry): Intragroup 14 and group 11-group 2 molecules / Ciccioli, Andrea; Gigli, Guido. - In: ECS TRANSACTIONS. - ISSN 1938-5862. - 46:1(2013), pp. 99-111. (Intervento presentato al convegno Workshop on Knudsen Effusion Mass Spectrometry tenutosi a Juelich nel 23 April 2012 through 25 April 2012) [10.1149/04601.0099ecst].
Determination of the dissociation energy of Diatomic Molecules by KEMS (Knudsen Effusion Mass Spectrometry): Intragroup 14 and group 11-group 2 molecules
CICCIOLI, Andrea;GIGLI, Guido
2013
Abstract
This contribution summarize our recent work devoted to detect and thermochemically characterise by KEMS experiments (Knudsen Effusion Mass Spectrometry) a number of diatomic gaseous molecules either never observed before or whose bond energy was unknown. The results obtained over the years for the intragroup 14 and the group 11-group 2 species are here collected and compared with quantum chemical calculations at the CCSD(T) level. © The Electrochemical Society.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
