The local elasticity of glasses is known to be inhomogeneous on a microscopic scale compared to that of crystalline materials. Their vibrational spectrum strongly deviates from that expected from Debye's elasticity theory: The density of states deviates from Debye's law, the sound velocity shows a negative dispersion in the boson-peak frequency regime and there is a strong increase of the sound attenuation near the boson-peak frequency. By comparing a mean-field theory of shear-elastic heterogeneity with a large-scale simulation of a soft-sphere glass we demonstrate that the observed anomalies in glasses are caused by elastic heterogeneity. By observing that the macroscopic bulk modulus is frequency independent we show that the boson-peak-related vibrational anomalies are predominantly due to the spatially fluctuating microscopic shear stresses. It is demonstrated that the boson-peak arises from the steep increase of the sound attenuation at a frequency which marks the transition from wave-like excitations to disorder-dominated ones.

Heterogeneous shear elasticity of glasses: the origin of the boson peak / Marruzzo, Alessia; Walter, Schirmacher; Andrea, Fratalocchi; Ruocco, Giancarlo. - In: SCIENTIFIC REPORTS. - ISSN 2045-2322. - 3:(2013), p. 1407. [10.1038/srep01407]

Heterogeneous shear elasticity of glasses: the origin of the boson peak.

MARRUZZO, ALESSIA;RUOCCO, Giancarlo
2013

Abstract

The local elasticity of glasses is known to be inhomogeneous on a microscopic scale compared to that of crystalline materials. Their vibrational spectrum strongly deviates from that expected from Debye's elasticity theory: The density of states deviates from Debye's law, the sound velocity shows a negative dispersion in the boson-peak frequency regime and there is a strong increase of the sound attenuation near the boson-peak frequency. By comparing a mean-field theory of shear-elastic heterogeneity with a large-scale simulation of a soft-sphere glass we demonstrate that the observed anomalies in glasses are caused by elastic heterogeneity. By observing that the macroscopic bulk modulus is frequency independent we show that the boson-peak-related vibrational anomalies are predominantly due to the spatially fluctuating microscopic shear stresses. It is demonstrated that the boson-peak arises from the steep increase of the sound attenuation at a frequency which marks the transition from wave-like excitations to disorder-dominated ones.
2013
01 Pubblicazione su rivista::01a Articolo in rivista
Heterogeneous shear elasticity of glasses: the origin of the boson peak / Marruzzo, Alessia; Walter, Schirmacher; Andrea, Fratalocchi; Ruocco, Giancarlo. - In: SCIENTIFIC REPORTS. - ISSN 2045-2322. - 3:(2013), p. 1407. [10.1038/srep01407]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/645301
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