Over the last two decades, ever increasing interest has been focused on -conjugated triple-bond-containing systems, namely, (poly)aryl acetylenes, as a very promising class of semiconducting materials, owing to the availability of flexible/efficient synthetic protocols and the new conception of their conformational and steric advantages. In this review, the major design/synthetic strategies used to obtain molecular aryl acetylene semiconductors are discussed. A brief discussion of their key properties as well as their performance in organic field-effect transistors and photovoltaic cell applications is also included.

Small Molecular Aryl Acetylenes: Chemically Tailoring High-Efficiency Organic Semiconductors for Solar Cells and Field-Effect Transistors / Broggi, Alessandra; Ivan, Tomasi; Luca, Bianchi; Assunta, Marrocchi; Luigi, Vaccaro. - In: CHEMPLUSCHEM. - ISSN 2192-6506. - ELETTRONICO. - 79:4(2014), pp. 486-507. [10.1002/cplu.201400001]

Small Molecular Aryl Acetylenes: Chemically Tailoring High-Efficiency Organic Semiconductors for Solar Cells and Field-Effect Transistors

BROGGI, ALESSANDRA;
2014

Abstract

Over the last two decades, ever increasing interest has been focused on -conjugated triple-bond-containing systems, namely, (poly)aryl acetylenes, as a very promising class of semiconducting materials, owing to the availability of flexible/efficient synthetic protocols and the new conception of their conformational and steric advantages. In this review, the major design/synthetic strategies used to obtain molecular aryl acetylene semiconductors are discussed. A brief discussion of their key properties as well as their performance in organic field-effect transistors and photovoltaic cell applications is also included.
2014
aryl acetylenes; cross-coupling; pi interactions; semiconductors; synthetic methods
01 Pubblicazione su rivista::01a Articolo in rivista
Small Molecular Aryl Acetylenes: Chemically Tailoring High-Efficiency Organic Semiconductors for Solar Cells and Field-Effect Transistors / Broggi, Alessandra; Ivan, Tomasi; Luca, Bianchi; Assunta, Marrocchi; Luigi, Vaccaro. - In: CHEMPLUSCHEM. - ISSN 2192-6506. - ELETTRONICO. - 79:4(2014), pp. 486-507. [10.1002/cplu.201400001]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/559866
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