Over the last two decades, ever increasing interest has been focused on -conjugated triple-bond-containing systems, namely, (poly)aryl acetylenes, as a very promising class of semiconducting materials, owing to the availability of flexible/efficient synthetic protocols and the new conception of their conformational and steric advantages. In this review, the major design/synthetic strategies used to obtain molecular aryl acetylene semiconductors are discussed. A brief discussion of their key properties as well as their performance in organic field-effect transistors and photovoltaic cell applications is also included.
Small Molecular Aryl Acetylenes: Chemically Tailoring High-Efficiency Organic Semiconductors for Solar Cells and Field-Effect Transistors / Broggi, Alessandra; Ivan, Tomasi; Luca, Bianchi; Assunta, Marrocchi; Luigi, Vaccaro. - In: CHEMPLUSCHEM. - ISSN 2192-6506. - ELETTRONICO. - 79:4(2014), pp. 486-507. [10.1002/cplu.201400001]
Small Molecular Aryl Acetylenes: Chemically Tailoring High-Efficiency Organic Semiconductors for Solar Cells and Field-Effect Transistors
BROGGI, ALESSANDRA;
2014
Abstract
Over the last two decades, ever increasing interest has been focused on -conjugated triple-bond-containing systems, namely, (poly)aryl acetylenes, as a very promising class of semiconducting materials, owing to the availability of flexible/efficient synthetic protocols and the new conception of their conformational and steric advantages. In this review, the major design/synthetic strategies used to obtain molecular aryl acetylene semiconductors are discussed. A brief discussion of their key properties as well as their performance in organic field-effect transistors and photovoltaic cell applications is also included.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.