A novel copper-catalyzed approach to benzils from readily available deoxybenzoins under neutral conditions using air as the oxidant has been developed. The reaction tolerates a variety of useful substituents including chloro, bromo, iodo, keto, ester, and cyano groups.
Copper-Catalyzed Oxidation of Deoxybenzoins to Benzils under Aerobic Conditions / Cacchi, Sandro; Fabrizi, Giancarlo; Goggiamani, Antonella; Iazzetti, Antonia; Verdiglione, Rosanna. - In: SYNTHESIS. - ISSN 0039-7881. - STAMPA. - 45:12(2013), pp. 1701-1707. [10.1055/s-0033-1338451]
Copper-Catalyzed Oxidation of Deoxybenzoins to Benzils under Aerobic Conditions
CACCHI, Sandro;FABRIZI, Giancarlo;GOGGIAMANI, ANTONELLA;IAZZETTI, Antonia;VERDIGLIONE, ROSANNA
2013
Abstract
A novel copper-catalyzed approach to benzils from readily available deoxybenzoins under neutral conditions using air as the oxidant has been developed. The reaction tolerates a variety of useful substituents including chloro, bromo, iodo, keto, ester, and cyano groups.File allegati a questo prodotto
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