We consider the theory of the glass phase and jamming of hard spheres in the large space dimension limit. Building upon the exact expression for the free-energy functional obtained previously, we find that the random first order transition (RFOT) scenario is realized here with two thermodynamic transitions: the usual Kauzmann point associated with entropy crisis and a further transition at higher pressures in which a glassy structure of microstates is developed within each amorphous state. This kind of glass–glass transition into a phase dominating the higher densities was described years ago by Elisabeth Gardner, and may well be a generic feature of RFOT. Microstates that are small excitations of an amorphous matrix—separated by low entropic or energetic barriers—thus emerge naturally, and modify the high pressure (or low temperature) limit of the thermodynamic functions.
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|Titolo:||Exact Theory of Dense Amorphous Hard Spheres in High Dimension. II. The High Density Regime and the Gardner Transition|
|Data di pubblicazione:||2013|
|Appartiene alla tipologia:||01a Articolo in rivista|