This paper represents the first step of a comprehensive analysis of the influence of CO2 in the DMFC channels. The flow is treated as gaseous (and not as liquid‐gaseous mixture) to separately assess the importance of several parameters, such as methanol concentration, mass flow, current density. In the model mass transport of the different species and the electric field inside the fuel cell are considered. The 3D computational model with multicomponent flow is solved using COMSOL Multiphysics software. The set of governing equations is composed by: a) Maxwell‐Stefan equation for species transport; b) Brinkman equation to calculate momentum in porous media; c) Butler‐Volmer equation to calculate the current density over the catalyst layers allowing the achievement of the quantity of generated/consumed species. The equations system is validated against available experimental data. The V/I characteristic of the cell, species distributions, velocity fields and current density distributions will be discussed. The generation and the dispersion of CO2 in the anode channel is also analyzed.
Simulation of fluid dynamic and electric field in a direct methanol fuel cell / Borello, Domenico; Calabriso, Andrea; Cedola, Luca; Rispoli, Franco. - (2013). (Intervento presentato al convegno International Conference on Applied Energy tenutosi a Pretoria, South Africa nel 1-4 Luglio 2013).
Simulation of fluid dynamic and electric field in a direct methanol fuel cell
BORELLO, Domenico;CALABRISO, ANDREA;CEDOLA, Luca;RISPOLI, Franco
2013
Abstract
This paper represents the first step of a comprehensive analysis of the influence of CO2 in the DMFC channels. The flow is treated as gaseous (and not as liquid‐gaseous mixture) to separately assess the importance of several parameters, such as methanol concentration, mass flow, current density. In the model mass transport of the different species and the electric field inside the fuel cell are considered. The 3D computational model with multicomponent flow is solved using COMSOL Multiphysics software. The set of governing equations is composed by: a) Maxwell‐Stefan equation for species transport; b) Brinkman equation to calculate momentum in porous media; c) Butler‐Volmer equation to calculate the current density over the catalyst layers allowing the achievement of the quantity of generated/consumed species. The equations system is validated against available experimental data. The V/I characteristic of the cell, species distributions, velocity fields and current density distributions will be discussed. The generation and the dispersion of CO2 in the anode channel is also analyzed.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.