New heterocyclic compounds characterized by the presence of a diaziridine and an oxaziridine ring directly bound were reported. A first desymmetrization reaction of α-diimines using nosyloxycarbamate as aminating agent in a H2O/CH2Cl2 system gives (E)-3-(iminomethyl) diaziridine-1-carboxylates which were further functionalized obtaining the never synthesized before 3-(diaziridin-3-yl)oxaziridines. © 2013 Elsevier Ltd. All rights reserved.
Desymmetrization of α-diimines: Synthesis of new 3-(diaziridin-3-yl) oxaziridines / Emanuele, Aresu; Laura, Carroccia; Fioravanti, Stefania; Pellacani, Lucio. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 54:34(2013), pp. 4574-4576. [10.1016/j.tetlet.2013.06.090]
Desymmetrization of α-diimines: Synthesis of new 3-(diaziridin-3-yl) oxaziridines
FIORAVANTI, Stefania;PELLACANI, Lucio
2013
Abstract
New heterocyclic compounds characterized by the presence of a diaziridine and an oxaziridine ring directly bound were reported. A first desymmetrization reaction of α-diimines using nosyloxycarbamate as aminating agent in a H2O/CH2Cl2 system gives (E)-3-(iminomethyl) diaziridine-1-carboxylates which were further functionalized obtaining the never synthesized before 3-(diaziridin-3-yl)oxaziridines. © 2013 Elsevier Ltd. All rights reserved.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
