Novel cyclometallated iridium-Pt/Pd dinuclear complexes containing the bridging ligand 2,2′:5′,2′′-terpyridine (BPP) and the peripheral phenylpyridine (ppy) ligand produced hydrogen under both visible (470 nm) and UV (350 nm) irradiation. The turnover numbers using visible light were found to be significantly higher, indicating an interplay between two independent excited states, only one of which produces H 2 efficiently. © 2012 The Royal Society of Chemistry.

Wavelength dependent photocatalytic H 2 generation using iridium-Pt/Pd complexes / Suraj, Soman; Gurmeet Singh, Bindra; Avishek, Paul; Robert, Groarke; Jennifer C., Manton; M., Connaughton Finn; Schulz, Martin; Dini, Danilo; Conor, Long; Mary T., Pryce; Johannes G., Vos. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - 41:41(2012), pp. 12678-12680. [10.1039/c2dt32028b]

Wavelength dependent photocatalytic H 2 generation using iridium-Pt/Pd complexes

DINI, DANILO;
2012

Abstract

Novel cyclometallated iridium-Pt/Pd dinuclear complexes containing the bridging ligand 2,2′:5′,2′′-terpyridine (BPP) and the peripheral phenylpyridine (ppy) ligand produced hydrogen under both visible (470 nm) and UV (350 nm) irradiation. The turnover numbers using visible light were found to be significantly higher, indicating an interplay between two independent excited states, only one of which produces H 2 efficiently. © 2012 The Royal Society of Chemistry.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11573/509734
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