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EnglishSome results and some general observations on the reactivity of different substrates in lipase-catalyzed reactions in supercritical carbon dioxide are reported. Chiral 1 -phenylethanol, 2-octanol, 6-methyl-5-hepten-2-ol and trans-3-penten-2-ol have been prepared in high enantiomeric excess (ee > 80%) by enantioselective acetylation of the corresponding racemic alcohols using immobilized crude lipase (Pseudomonas sp. from Amano) in supercritical carbon dioxide.
http://hdl.handle.net/11573/50302| Titolo: | Enantioselectivity and reactivity of immobilized lipase in supercritical carbon dioxide |
| Autori interni: | PALOCCI, Cleofe MISITI, Domenico GASPARRINI, Francesco CERNIA, Enrico |
| Data di pubblicazione: | 1994 |
| Rivista: | JOURNAL OF MOLECULAR CATALYSIS |
| Abstract: | Some results and some general observations on the reactivity of different substrates in lipase-catalyzed reactions in supercritical carbon dioxide are reported. Chiral 1 -phenylethanol, 2-octanol, 6-methyl-5-hepten-2-ol and trans-3-penten-2-ol have been prepared in high enantiomeric excess (ee > 80%) by enantioselective acetylation of the corresponding racemic alcohols using immobilized crude lipase (Pseudomonas sp. from Amano) in supercritical carbon dioxide. |
| Handle: | http://hdl.handle.net/11573/50302 |
| Appare nelle tipologie: | 01.a Pubblicazione su Rivista |
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