The reactions of both ground, 3P, and electronically excited, 1D, oxygen atoms with H 2S were studied using crossed molecular beam method. The reactions which lead to HSO+H for the O( 3P), and to HSO/HSO+H and SO_H 2 for the O( 1D) reactions were also studied. The dynamics of the channels which lead to HSO/HSO+H were elucidated for the reactions of both states. The enthalpy of formation of the HSO radical was analyzed and their conformity with the experimental data was evaluated.

Crossed beam studies of the reactions of atomic oxygen in the ground 3P and first electronically excited 1D states with hydrogen sulfide / N., Balucani; Stranges, Domenico; P., Casavecchia; G. G., Volpi. - In: THE JOURNAL OF CHEMICAL PHYSICS. - ISSN 0021-9606. - STAMPA. - 120:20(2004), pp. 9571-9582. [10.1063/1.1714809]

Crossed beam studies of the reactions of atomic oxygen in the ground 3P and first electronically excited 1D states with hydrogen sulfide

STRANGES, Domenico;
2004

Abstract

The reactions of both ground, 3P, and electronically excited, 1D, oxygen atoms with H 2S were studied using crossed molecular beam method. The reactions which lead to HSO+H for the O( 3P), and to HSO/HSO+H and SO_H 2 for the O( 1D) reactions were also studied. The dynamics of the channels which lead to HSO/HSO+H were elucidated for the reactions of both states. The enthalpy of formation of the HSO radical was analyzed and their conformity with the experimental data was evaluated.
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Crossed beam studies of the reactions of atomic oxygen in the ground 3P and first electronically excited 1D states with hydrogen sulfide / N., Balucani; Stranges, Domenico; P., Casavecchia; G. G., Volpi. - In: THE JOURNAL OF CHEMICAL PHYSICS. - ISSN 0021-9606. - STAMPA. - 120:20(2004), pp. 9571-9582. [10.1063/1.1714809]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/50029
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