We consider the thermodynamic potential describing the macroscopic fluctuation of the current and local energy of a general class of Hamiltonian models including aerogels. We argue that this potential is neither analytic nor strictly convex, a property that should be expected in general but is missing from models studied in the literature. This opens the possibility of describing in terms of a thermodynamic potential non-equilibrium phase transitions in a concrete physical context. This special behavior of the thermodynamic potential is caused by the fact that the energy current is carried by particles which may have arbitrary low speed with sufficiently large probability.
Macroscopic fluctuation theory of aerogel dynamics / Raphaël, Lefevere; Mariani, Mauro; Lorenzo, Zambotti. - In: JOURNAL OF STATISTICAL MECHANICS: THEORY AND EXPERIMENT. - ISSN 1742-5468. - STAMPA. - 2010:12(2010), p. L12004. [10.1088/1742-5468/2010/12/l12004]
Macroscopic fluctuation theory of aerogel dynamics
MARIANI, Mauro;
2010
Abstract
We consider the thermodynamic potential describing the macroscopic fluctuation of the current and local energy of a general class of Hamiltonian models including aerogels. We argue that this potential is neither analytic nor strictly convex, a property that should be expected in general but is missing from models studied in the literature. This opens the possibility of describing in terms of a thermodynamic potential non-equilibrium phase transitions in a concrete physical context. This special behavior of the thermodynamic potential is caused by the fact that the energy current is carried by particles which may have arbitrary low speed with sufficiently large probability.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.