The title compound, C8H11N2O+·CH3CO2 -, was synthesized by a reaction between 4-methoxybenzamidine (4-amidinoanisole) and acetic acid. In the cation, the amidinium group forms a dihedral angle of 11.65 (17)°with the mean plane of the benzene ring. The ionic components are associated in the crystal via N-H+⋯O- hydrogen bonds, resulting in a one-dimensional structure consisting of dimers and catemers and orientated approximately along the c axis.

4-Methoxybenzamidinium acetate / Irrera, Simona; Portalone, Gustavo. - In: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE. - ISSN 1600-5368. - STAMPA. - 68:12(2012), pp. o3277-o3277. [10.1107/s1600536812044911]

4-Methoxybenzamidinium acetate

IRRERA, SIMONA;PORTALONE, Gustavo
2012

Abstract

The title compound, C8H11N2O+·CH3CO2 -, was synthesized by a reaction between 4-methoxybenzamidine (4-amidinoanisole) and acetic acid. In the cation, the amidinium group forms a dihedral angle of 11.65 (17)°with the mean plane of the benzene ring. The ionic components are associated in the crystal via N-H+⋯O- hydrogen bonds, resulting in a one-dimensional structure consisting of dimers and catemers and orientated approximately along the c axis.
2012
data-to-parameter ratio = 15.2; mean ω(c-c) = 0.003 å; r factor = 0.056; single-crystal x-ray study; t = 298 k; wr factor = 0.141
01 Pubblicazione su rivista::01a Articolo in rivista
4-Methoxybenzamidinium acetate / Irrera, Simona; Portalone, Gustavo. - In: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE. - ISSN 1600-5368. - STAMPA. - 68:12(2012), pp. o3277-o3277. [10.1107/s1600536812044911]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/490022
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