Molar absorptivities and equil. consts. for 1:1, 1:2, 1:3, and 2:1 Cr3+ and Fe3+ complexes with pyridine-2-aldoxime were detd. in 0.5M NaClO4 at 25° by spectrophotometry. Hydrolysis occurs above pH 5.5 and 4.0, resp. The mononuclear complexes contain only M-N bonds (to oxime and pyridine N). The dinuclear complexes must contain M-O bonds (to oxime O
Reaction of chromium(III) and iron(III) with pyridine-2-aldoxime in acidic aqueous medium / Chiacchierini, E.; Petrone, V.; Magri', Antonio. - In: GAZZETTA CHIMICA ITALIANA. - ISSN 0016-5603. - STAMPA. - 105:3-4(1975), pp. 205-220.
Reaction of chromium(III) and iron(III) with pyridine-2-aldoxime in acidic aqueous medium
MAGRI', Antonio
1975
Abstract
Molar absorptivities and equil. consts. for 1:1, 1:2, 1:3, and 2:1 Cr3+ and Fe3+ complexes with pyridine-2-aldoxime were detd. in 0.5M NaClO4 at 25° by spectrophotometry. Hydrolysis occurs above pH 5.5 and 4.0, resp. The mononuclear complexes contain only M-N bonds (to oxime and pyridine N). The dinuclear complexes must contain M-O bonds (to oxime OFile allegati a questo prodotto
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