The dramatic effects of the size and hydrophilic/hydrophobic properties of cavities on the intrinsic reaction kinetics and dynamics is shown by the gas-phase reaction of (R)-(-)-2-butylamine and complexes of stereoisomeric amido[4]resorcinarene hosts with aromatic amino acids. The graph shows the kinetic plots of the base-induced loss of L-Phe (green), L-Tyr (red), and L-dopa (blue).
Cavity effects on the enantioselectivity of chiral amido[4]resorcinarene stereoisomers / Botta, Bruno; D., Subissati; A., Tafi; G. D., Monache; Filippi, Antonello; Speranza, Maurizio. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 43:(2004), pp. 4767-4770. [10.1002/anie.200460663]
Cavity effects on the enantioselectivity of chiral amido[4]resorcinarene stereoisomers
BOTTA, Bruno;FILIPPI, Antonello;SPERANZA, Maurizio
2004
Abstract
The dramatic effects of the size and hydrophilic/hydrophobic properties of cavities on the intrinsic reaction kinetics and dynamics is shown by the gas-phase reaction of (R)-(-)-2-butylamine and complexes of stereoisomeric amido[4]resorcinarene hosts with aromatic amino acids. The graph shows the kinetic plots of the base-induced loss of L-Phe (green), L-Tyr (red), and L-dopa (blue).I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
