Gaseous Bz+ were prepd. by treatment of CO with Ph+ formed by β-decay of polytritiated benzene. Bz+ reacts selectively with ambident arom. substrates, e.g. PhNH2, PhOH, with a marked bias in favor of n-type nucleophilic centers and do not react appreciably with the π-system, even when strongly activated as in C6HMe5.

Gas-phase reaction of benzoyl cation with arenes. High selectivity of a gaseous, charged electrophile / G., Occhiucci; Speranza, Maurizio; Cacace, Fulvio. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - STAMPA. - 11(1984), pp. 723-724.

Gas-phase reaction of benzoyl cation with arenes. High selectivity of a gaseous, charged electrophile

SPERANZA, Maurizio;CACACE, Fulvio
1984

Abstract

Gaseous Bz+ were prepd. by treatment of CO with Ph+ formed by β-decay of polytritiated benzene. Bz+ reacts selectively with ambident arom. substrates, e.g. PhNH2, PhOH, with a marked bias in favor of n-type nucleophilic centers and do not react appreciably with the π-system, even when strongly activated as in C6HMe5.
1984
01 Pubblicazione su rivista::01a Articolo in rivista
Gas-phase reaction of benzoyl cation with arenes. High selectivity of a gaseous, charged electrophile / G., Occhiucci; Speranza, Maurizio; Cacace, Fulvio. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - STAMPA. - 11(1984), pp. 723-724.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/466381
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