A new and convenient procedure for the prepn. of α-iodo ketones from the corresponding enol silyl ether or enol acetate with I2 and copper(II) nitrate in CH3CN is reported. The method shows wide applicability and very good yields (85-100%).
Reaction of enol silyl ethers and enol acetates with copper(II) nitrate-iodine: synthesis of .alpha.-iodo ketones / DALLA CORT, Antonella. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - STAMPA. - 56:(1991), pp. 6708-6709. [10.1021/jo00023a042]
Reaction of enol silyl ethers and enol acetates with copper(II) nitrate-iodine: synthesis of .alpha.-iodo ketones
DALLA CORT, Antonella
1991
Abstract
A new and convenient procedure for the prepn. of α-iodo ketones from the corresponding enol silyl ether or enol acetate with I2 and copper(II) nitrate in CH3CN is reported. The method shows wide applicability and very good yields (85-100%).File allegati a questo prodotto
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