The reactivity of the phthalimide N-oxyl radical (PINO) toward the OH bond of a series of substituted phenols was kinetically investigated in CH3CN. The reaction selectivity and the deuterium kinetic isotope effect were determined. Information on the kinetic solvent effect was also obtained with phenol as the substrate.
Reactivity of phthalimide N-oxyl radical (PINO) toward the phenolic O-H bond. A kinetic study / Baciocchi, Enrico; Gerini, Maria Francesca; Lanzalunga, Osvaldo. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - 69:(2004), pp. 8963-8966. [10.1021/jo048656o]
Reactivity of phthalimide N-oxyl radical (PINO) toward the phenolic O-H bond. A kinetic study
BACIOCCHI, Enrico;GERINI, Maria Francesca;LANZALUNGA, Osvaldo
2004
Abstract
The reactivity of the phthalimide N-oxyl radical (PINO) toward the OH bond of a series of substituted phenols was kinetically investigated in CH3CN. The reaction selectivity and the deuterium kinetic isotope effect were determined. Information on the kinetic solvent effect was also obtained with phenol as the substrate.File allegati a questo prodotto
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